Given distinct $c_0,\ldots,c_n\in F$, there are unique polynomials $p_0,\ldots,p_n\in Pol_n(F)$ such that $p_i(c_j)=1$ if $i=j$, $=0$ otherwise. (These Lagrange interpolation polynomials are given by explicit formulas, which you must know.)
Theorem: The Lagrange interpolation polynomials $p_0,\ldots,p_n$ form a basis of the vector space $Pol_n(F)$.
(Idea of proof: they are linearly independent, and there are $n+1$ of them.) Given $a_0,\ldots,a_n\in F$, there is a unique polynomial $p\in Pol_n(F)$ such that $p(c_i)=a_i$, given by the linear combination $p=a_0p_0+\ldots+a_np_n$. Make sure to practise this in concrete examples! (Note also that for finite fields, we must have $n<\# F$ in the discussion, since the $c_0,\ldots,c_n$ must be distinct.)